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26 Although there is abundant in chemico evidence that aldehyde toxicants can form adducts with lysine and histidine residues on proteins, 60−64 the relatively high aldehyde-to-protein ratios (e.g., 50:1) and long incubation times (≥24 h) needed to produce these adducts reflect the very slow rate of adduct formation between a soft aldehyde electrophile and a significantly harder amino acid nucleophile